ColorPic is a handy color grabber. It’ll pick colors from any window, wherever your mouse pointer is pointing. Not perfect, but handy and free. Unfortunately it doesn’t seem to save the palettes in any conventional palette format, but in the app’s directory there’s an XML file if you need some portability for the palettes you create in ColorPic.
Get it here.
On the topic of palettes though, Adobe’s Kuler Flash app is great.
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